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1 article(s) from Löschmann, Thomas

A superior P-H phosphonite: Asymmetric allylic substitutions with fenchol- based palladium catalysts

Bernd Goldfuss,
Thomas Löschmann,
Tina Kop-Weiershausen,
Jörg Neudörfl and
Frank Rominger

Beilstein J. Org. Chem. 2006, 2, No. 7, doi:10.1186/1860-5397-2-7

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Scheme 1: Pd-catalyzed allylic substitution with unsymmetrical substrates (Nu = dimethylmalonate, Nf = OAc).

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Scheme 2: Bidentate P, N-ligands and a monodentate phosphoramidite for Pd-catalyzed allylic substitutions wit...

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Scheme 3: Fenchole-based phosphorus ligands (i.e. FEENOPs and BIFOPs) for Pd-catalyzed allylic substitutions....

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Scheme 4: Allylic alkylation of 1-phenyl-2-propenyl acetate by sodium dimethylmalonate (BSA-method) with Pd-F...

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Figure 1: X-ray crystal structure of the cationic complex Pd-FENOP (CCDC 299944), the perchlorate counterion ...

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Figure 2: X-ray crystal structure of the cationic complex Pd-FENOP-Me (CCDC 600369), the perchlorate counteri...

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Figure 3: X-ray crystal structure of the cationic complex Pd-FENOP-NMe₂ (CCDC 600370), the perchlorate counte...

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Figure 4: The two most stable ONIOM(B3LYP/SDD(+ECP) (Pd) /6-31G* (C, H, O, N, P) : UFF) optimized transition ...

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Figure 5: The two most stable ONIOM(B3LYP/SDD(+ECP) (Pd) /6-31G* (C, H, O, N, P) : UFF) optimized transition ...

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Published 30 Mar 2006

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